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Colorless clear Liquid Tetramethylene Sulfone Sulfolane CAS 126-33-0

CAS No.:21245-02-3
Place of Origin:China
Appearance:Pale yellow liquid
MF:C17H27NO2
Purity:99%
Certificate:COA MSDS TDS
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Sulfolane—chemically known as tetrahydrothiophene-1,1-dioxide—is a high-boiling, aprotic polar solvent. Its molecular structure consists of a five-membered ring containing one sulfur atom and two oxygen atoms (forming a sulfone group). This substance was first successfully developed by Shell in the 1940s and quickly gained widespread application within the petrochemical and natural gas industries.

As an excellent solvent, sulfolane possesses exceptional dissolving power and high selectivity. It exhibits a strong affinity for aromatic hydrocarbons (such as benzene, toluene, and xylene) while demonstrating low solubility toward aliphatic hydrocarbons. This characteristic makes it an ideal extractant for the industrial recovery of aromatics from reformate, and it is widely utilized in the production processes for benzene, toluene, and xylene (BTX).

 

Product picture:
Sulfolane
Sulfolane
Function

Aromatic extraction constitutes the primary application field for sulfolane. In the petroleum refining industry, sulfolane is frequently employed as an extraction solvent to recover benzene, toluene, and xylene (BTX) from catalytic reformate or cracked gasoline. By leveraging sulfolane’s high solubility for aromatics—and conversely, its low solubility for non-aromatics (aliphatic and naphthenic hydrocarbons)—aromatics can be efficiently separated from complex hydrocarbon mixtures through a liquid-liquid extraction process. The Sulfolane Aromatic Extraction (SAE) process developed by Sinopec is characterized by high product purity, high yield, and strong adaptability, and it is widely utilized in domestic refineries.

Sulfolane also serves as a key solvent in the purification of natural gas and synthesis gas. It is often used in combination with diisopropanolamine (DIPA) or methyldiethanolamine (MDEA) to form the “Sulfolane-Amine” desulfurization process. This method capitalizes on sulfolane’s high solubility for acidic gases (such as H₂S and CO₂) alongside the chemical absorption capabilities of amines; this dual action enables the efficient removal of acidic components from gas streams, thereby meeting the stringent industrial requirements for purified gases.

In the fields of fine chemicals and organic synthesis, sulfolane frequently functions as a reaction medium or solvent. Due to its high polarity, high boiling point, and excellent thermal stability, it facilitates a variety of reactions—including Friedel-Crafts acylation, halogen exchange, oxidation, and nitration—thereby enhancing reaction rates and product yields. Furthermore, sulfolane can serve as a solvent for polymers or as a spinning solvent in the production of materials such as polyacrylonitrile and polyvinyl chloride, contributing to improved fiber properties.

 

Product Specifications:

Item Quality Index Analyse Method
Appearance colorless or canary lucid liquid Eyeballing
Density(30°C) kg/m3 1260-1270 ASTM  D  4052
5%Distil of temperature °C ≥282 ASTM  D  1078
95% Distil of temperature °C ≤288
Thermal stability  mgSO2/kg ≤20 UOP 599
Moisture   %(m/m) ≤3.0 UOP 481
Sulfur Content  %(m/m) 26.0-27.0 ASTM D 1078
2-Sulfolene   %(m/m) ≤0.2 UOP  608
Isopropyl sulfolane eather %(m/m) ≤0.2 UOP  608
Ash content  %(m/m) ≤0.1

ASTM  D  482

 

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Sulfolane package
Sulfolane package

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